Cyanotrichite
A valid IMA mineral species - grandfathered
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About Cyanotrichite
Formula:
Cu4Al2(SO4)(OH)12 ยท 2H2O
Colour:
Sky-blue, azure-blue
Lustre:
Silky
Hardness:
1 - 3
Specific Gravity:
2.76
Crystal System:
Monoclinic
Member of:
Name:
From the Greek ฮบฯ
ฮฑฮฝฯฯ for "blue" and ฮธฯฮฏฮพ for "hair" in allusion to its colour and habit.
Cyanotrichite Group.
A secondary copper mineral found sparsely in the oxidation zones of copper-bearing ore bodies.
Cyanotrichite is closely related to Carbonatecyanotrichite, from which it is impossible to distinguish without XRD measurements (tests for carbonate are not conclusive). Improved powder data are recently given by Hager et al. (2009) who suggest that there is no evidence for a solid solution series between cyanotrichite and carbonate-cyanotrichite; it is also evident that some carbonate-cyanotrichite specimens contain no sulfate.
The nomenclature situation is still complicated because the crystal structures of neither mineral is presently known (Nov. 2022 update: no longer a case since the Mills et al. 2015 paper on the structure of cyanotrichite).
See also Unnamed (Cyanotrichite-related mineral).
Visually similar to Khaidarkanite.
A secondary copper mineral found sparsely in the oxidation zones of copper-bearing ore bodies.
Cyanotrichite is closely related to Carbonatecyanotrichite, from which it is impossible to distinguish without XRD measurements (tests for carbonate are not conclusive). Improved powder data are recently given by Hager et al. (2009) who suggest that there is no evidence for a solid solution series between cyanotrichite and carbonate-cyanotrichite; it is also evident that some carbonate-cyanotrichite specimens contain no sulfate.
The nomenclature situation is still complicated because the crystal structures of neither mineral is presently known (Nov. 2022 update: no longer a case since the Mills et al. 2015 paper on the structure of cyanotrichite).
See also Unnamed (Cyanotrichite-related mineral).
Visually similar to Khaidarkanite.
Unique Identifiers
Mindat ID:
1203
Long-form identifier:
mindat:1:1:1203:0
IMA Classification of Cyanotrichite
Approved, 'Grandfathered' (first described prior to 1959)
IMA Formula:
Cu2+4Al2S6+O4(OH)12ยท2H2O
Classification of Cyanotrichite
7.DE.10
7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
D : Sulfates (selenates, etc.) with additional anions, with H2O
E : With only medium-sized cations; unclassified
7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
D : Sulfates (selenates, etc.) with additional anions, with H2O
E : With only medium-sized cations; unclassified
31.2.1.1
31 : HYDRATED SULFATES CONTAINING HYDROXYL OR HALOGEN
2 : (AB)6(XO4)Zq·xH2O
31 : HYDRATED SULFATES CONTAINING HYDROXYL OR HALOGEN
2 : (AB)6(XO4)Zq·xH2O
25.2.20
25 : Sulphates
2 : Sulphates of Cu and Ag
25 : Sulphates
2 : Sulphates of Cu and Ag
Mineral Symbols
As of 2021 there are now IMAโCNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
| Symbol | Source | Reference for Standard |
|---|---|---|
| Cya | IMAโCNMNC | Warr, L.N. (2021). IMAโCNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Cyanotrichite
Silky
Transparency:
Transparent, Translucent
Colour:
Sky-blue, azure-blue
Streak:
Light blue
Hardness:
1 - 3 on Mohs scale
Density:
2.76 g/cm3 (Measured)
Comment:
A range from 2.737 (Morenci material) to 2.95 (Cap Garonne ?) exists in the literature.
Optical Data of Cyanotrichite
Type:
Biaxial (+)
RI values:
nα = 1.588 nβ = 1.617 nγ = 1.655
2V:
Measured: 82° , Calculated: 86°
Max. Birefringence:
δ = 0.067
Based on recorded range of RI values above.
Based on recorded range of RI values above.
Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.
Michel-Levy Bar The default colours simulate the birefringence range for a 30 ยตm thin-section thickness. Adjust the slider to simulate a different thickness.
Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.
Michel-Levy Bar The default colours simulate the birefringence range for a 30 ยตm thin-section thickness. Adjust the slider to simulate a different thickness.
Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.
Surface Relief:
High (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).
Relative to Canada balsam mounting medium (n ≈ 1.537).
This shows the grain boundary and Becke line effect under plane-polarised
light, based on the contrast between this mineral's average refractive
index and the mounting medium. It does not take into account mineral
colouration.
In focus
Interference Figure:
This shows the idealized biaxial acute bisectrix (Bxa) interference figure
- the conoscopic view for a grain cut perpendicular to the acute bisectrix, using
this mineral's 2V. The two small white dots mark the melatopes - the points
where the two optic axes emerge - and are shown only when they fall within the
field of view. The coloured bands are isochromatics, and the dark bands are
isogyres.
Rotate the stage: at 0°/90° the isogyres form a cross through the melatopes; at 45° they pull apart into curved hyperbolas. That splitting on rotation - absent in a uniaxial figure - is the standard diagnostic test for telling biaxial minerals from uniaxial ones. If 2V is large, the melatopes may fall outside the field of view, as they often do at the microscope too.
Rotate the stage: at 0°/90° the isogyres form a cross through the melatopes; at 45° they pull apart into curved hyperbolas. That splitting on rotation - absent in a uniaxial figure - is the standard diagnostic test for telling biaxial minerals from uniaxial ones. If 2V is large, the melatopes may fall outside the field of view, as they often do at the microscope too.
Dispersion:
relatively strong
Optical Extinction:
X = โฅ c (elongation); Z = c.
Pleochroism:
Visible
Comments:
X = nearly colourless; Y = light blue; Z = bright blue.
Chemistry of Cyanotrichite
Mindat Formula:
Cu4Al2(SO4)(OH)12 ยท 2H2O
Element Weights:
Crystallography of Cyanotrichite
Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
B2/m
Setting:
C2/m
Cell Parameters:
a = 12.625(3) Å, b = 2.8950(6) Å, c = 10.153(2) Å
β = 92.17(3)°
β = 92.17(3)°
Ratio:
a:b:c = 4.361 : 1 : 3.507
Unit Cell V:
370.82 ร
ยณ (Calculated from Unit Cell)
Morphology:
Occurs as velvet-, wool- or cotton-like aggregates and coatings comprised of minute acicular crystals; also radial-fibrous or tufted.
Comment:
Originally assumed to be orthorhombic, with the unit-cell parameters 10.16, 12.61, 2.90.
X-Ray Powder Diffraction
Powder Diffraction Data:
| d-spacing | Intensity |
|---|---|
| 10.2 ร | (100) |
| 5.47 ร | (50) |
| 5.26 ร | (80) |
| 3.88 ร | (90) |
| 3.38 ร | (35) |
| 3.04 ร | (40) |
| 2.392 ร | (35) |
Comments:
Grandview mine, Arizona, USA (ICDD-PDF no. 11โ131)
Geological Environment
Paragenetic Mode(s):
| Paragenetic Mode | Earliest Age (Ga) |
|---|---|
| Stage 7: Great Oxidation Event | <2.4 |
| 47a : [Near-surface hydration of prior minerals] | |
| 47b : [Sulfates and sulfites] | |
| 47c : [Carbonates, phosphates, borates, nitrates] |
Type Occurrence of Cyanotrichite
Place of Conservation of Type Material:
Technische Universitรคt, Bergakademie Freiberg, Freiberg, Germany, numbers 105613, 105616.
Synonyms of Cyanotrichite
Other Language Names for Cyanotrichite
Relationship of Cyanotrichite to other Species
Member of:
Other Members of Cyanotrichite Group:
| Camรฉrolaite | Cu6Al3(OH)18(H2O)2[Sb(OH)6](SO4) | Tric. 1 : P1 |
| Carbonatecyanotrichite | Cu4Al2(CO3,SO4)(OH)12 ยท 2H2O | Mon. 2/m : B2/m |
| Khaidarkanite | Cu4Al3(OH)14F3 ยท 2H2O | Mon. 2/m : B2/m |
Common Associates
Associations Based on Photo Data:
| 270 photos of Cyanotrichite associated with Brochantite | Cu4(SO4)(OH)6 |
| 187 photos of Cyanotrichite associated with Malachite | Cu2(CO3)(OH)2 |
| 103 photos of Cyanotrichite associated with Azurite | Cu3(CO3)2(OH)2 |
| 86 photos of Cyanotrichite associated with Chalcoalumite | CuAl4(SO4)(OH)12 ยท 3H2O |
| 61 photos of Cyanotrichite associated with Parnauite | Cu9(AsO4)2(SO4)(OH)10 ยท 7H2O |
| 57 photos of Cyanotrichite associated with Chalcophyllite | Cu18Al2(AsO4)4(SO4)3(OH)24 ยท 36H2O |
| 46 photos of Cyanotrichite associated with Spangolite | Cu6Al(SO4)(OH)12Cl ยท 3H2O |
| 33 photos of Cyanotrichite associated with Grandviewite | Cu3Al2(SO4)(OH)10 ยท H2O |
| 30 photos of Cyanotrichite associated with Quartz | SiO2 |
| 23 photos of Cyanotrichite associated with Gypsum | CaSO4 ยท 2H2O |
Related Minerals - Strunz-mindat Grouping
| 7.DE. | Magnesioalterite | Mg2Fe3+4(SO4)4(C2O4)2(OH)4 ยท 17H2O |
| 7.DE. | Fabritzite | Zn9(SO4)2(OH)12Cl2 ยท 6H2O |
| 7.DE. | Cossaite | (Mg0.5,โป)Al6(SO4)6(HSO4)F6 ยท 36H2O |
| 7.DE. | Downsite | K2(MoO3)3(SO4) ยท 4H2O |
| 7.DE. | Liangjunite | K2(Mo2O5)(SO4)2 ยท 3H2O |
| 7.DE.05 | Mangazeite | Al2(SO4)(OH)4 ยท 3H2O |
| 7.DE.10 | 'UKI-1975-(SO:AlCu)' | (Cu, Al, SO4, H2O) |
| 7.DE.10 | Carbonatecyanotrichite | Cu4Al2(CO3,SO4)(OH)12 ยท 2H2O |
| 7.DE.15 | Schwertmannite | Fe3+16(OH,SO4)12-13O16 ยท 10-12H2O |
| 7.DE.20 | Tlalocite | Cu10Zn6(Te6+O4)2(Te4+O3)(OH)25Cl ยท 27H2O |
| 7.DE.25 | Utahite | MgCu4Zn2Te6+3O14(OH)4 ยท 6H2O |
| 7.DE.35 | Coquandite | Sb6+xO8+x(SO4)(OH)x(H2O)1- x (x = 0.3) |
| 7.DE.40 | Osakaite | Zn4(SO4)(OH)6 ยท 5H2O |
| 7.DE.42 | Alterite | Zn2Fe3+4(SO4)4(C2O4)2(OH)4 ยท 17H2O |
| 7.DE.45 | Barrotite | Cu9Al(HSiO4)2[(SO4)(HAsO4)0.5](OH)12 ยท 8H2O |
| 7.DE.45 | Wilcoxite | MgAl(SO4)2F ยท 17H2O |
| 7.DE.47 | Tiberiobardiite | {Cu9Al[SiO3(OH)]2(OH)12(H2O)6}(SO4)1.5 ยท 10H2O |
| 7.DE.50 | Bouลกkaite | (MoO2)2O(SO3OH)2(H2O)4 |
| 7.DE.50 | Stanleyite | (V4+O)(SO4) ยท 6H2O |
| 7.DE.57 | 'Khangalasite' | Fe(SO4)(OH) ยท 2H2O |
| 7.DE.60 | Hydrobasaluminite | Al4(SO4)(OH)10 ยท 12-36H2O |
| 7.DE.62 | Volaschioite | Fe4(SO4)O2(OH)6 ยท 2H2O |
| 7.DE.65 | Zaherite | Al12(SO4)5(OH)26 ยท 20H2O |
| 7.DE.75 | Camรฉrolaite | Cu6Al3(OH)18(H2O)2[Sb(OH)6](SO4) |
Other Information
Notes:
Soluble in acids.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Cyanotrichite
mindat.org URL:
https://www.mindat.org/min-1203.html
Please feel free to link to this page.
Please feel free to link to this page.
Search Engines:
External Links:
Mineral Dealers:
References for Cyanotrichite
Reference List:
Jameson, R. (1816) A System of Mineralogy. second edition, 3 volumes: 3: 153 (as Velvet Copper Ore).
Breithaupt, August (1823) Vollstรคndige Charakteristik des Mineral-Systems (1st ed.). Arnoldischen Buchhandlung.p.168 - as Sammeterz
Prior, G. T. (1889) Note on Connellite from a New Locality. Mineralogical Magazine, 8 (39) 182 doi:10.1180/minmag.1889.008.39.03 (referring to 'namaqualite' from Namaqualand)
Hager, S. L., Leverett, P., Williams, P. A. (2009) Possible Structural and Chemical Relationships in the Cyanotrichite Group. The Canadian Mineralogist, 47 (3) 635-648 doi:10.3749/canmin.47.3.635
Mills, S. J., Christy, A. G., Schnyder, C., Favreau, G., Price, J. R. (2014) The crystal structure of camerolaite and structural variation in the cyanotrichite family of merotypes. Mineralogical Magazine, 78 (7) 1527-1552 doi:10.1180/minmag.2014.078.7.02
Localities for Cyanotrichite
Showing 250 localities.
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
โ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
All localities listed without proper references should be considered as questionable.
Argentina | |
| Marquez-Zavalia et al. (1994) +1 other reference |
| Mรกrquez-Zavalรญa et al. (2020) | |
| Mรกrquez-Zavalรญa et al. (2020) | |
| Dominik Schlรคfli collection |
| Perellรณ et al. (2023) |
Australia | |
| Birch (1999) |
| Day et al. (1996) |
| Greg Dainty |
Austria | |
| Niedermayr et al. (1998) |
| Mikl et al. (2014) |
| Auer (2023) |
| Meixner (1976) +2 other references |
| Auer (2005) |
| Collection of NHM |
| Seemann (1993) +1 other reference |
| Seemann et al. (1987) +1 other reference |
| Seemann (1993) | |
| Schnorrer et al. (2000) |
| Neschen (n.d.) |
| Kolitsch et al. (2008) |
| Brandstรคtter et al. (2010) +1 other reference |
| Gerald Gesselbauer (06.2010) +1 other reference |
| Grรถbner (2005) |
| Taucher (1999) |
| Grรถbner (2005) |
| Kolitsch (2010) |
| Kolitsch (2010) |
| Exel (1993) |
| Kolitsch et al. (2022) |
Canada | |
| Jambor (1960) |
| Sabina (1992) |
Chile | |
| M.Dini collection |
| |
| collected and analysed by french ... |
| A.Molina & M. Dini collections |
| maurizio dini - analysed by EDX & PDF (by dr. Jochen Scluter) |
| Samples analysed by Dr. Jochen Schlรผter (Hamburg University) +1 other reference |
China | |
| Fabre (n.d.) |
| Shen (n.d.) |
Czech Republic | |
| Sejkora et al. (2006) |
| |
DR Congo | |
| Forrest Group |
| Gauthier et al. (1989) |
France | |
| Queneau (n.d.) |
| P.-C. Guiollard (2002) +1 other reference |
| Mourey (2017) |
| OLLIC Pascal Collection | |
| Hartmut Hensel Collection |
| Bari (1982) |
| Wittern et al. (1997) |
| Gineste et al. (2026) |
| Collection and Collected by (Font Philippe) |
| Cooper (1997) |
| www.zampano.com (n.d.) +1 other reference |
| Berbain et al. (2005) |
| Queneau (n.d.) |
| Queneau (n.d.) |
| Favreau et al. (1999) |
| Queneau (n.d.) |
| Robin Fialip 2013 |
| Queneau (n.d.) |
| BERBAIN et al. (2010) |
| Berbain et al. (2007) |
| Palache et al. (1951) +3 other references |
| CLAUDE Jean-Marie : trouvaille (08/1980) +1 other reference | |
| Favreau et al. (2024) | |
Germany | |
| 50. (in German) +4 other references |
| Walenta (1992) |
| Walenta (1992) | |
| Blessing et al. (1991) |
| Weiร (1990) |
| Schellhorn (1989) |
| "Lithothek" collection of the ... | |
| |
| Grรถbner et al. (2011) |
| Luetcke (n.d.) | |
| Schnorrer-Kรถhler (1991) |
| Stieglitz et al. (1989) |
| Bender et al. (1994) |
| Wittern (2001) |
| Heinrich et al. (2006) |
| Thomas Lรผhr Collection |
| Grรถbner et al. (2011) |
| Grรถbner et al. (2011) |
| Grรถbner et al. (2006) |
| EDX and RAMAN analysis by Joy Desor |
Greece | |
| Wendel (2000) +2 other references |
| Rieck et al. (1999) +1 other reference | |
| Hanke (1998) |
| Grรถbner (2001) | |
| Ko Jansen |
| Gelaude et al. (1996) | |
| |
| Uwe Kolitsch (unpublished SEM-EDS analyses) | |
Italy | |
| Ratto et al. (1967) +2 other references |
| Sylvano IOB Collection +1 other reference |
| Palenzona A. (1991) |
| Orlandi et al. (1) |
| Gruppo Mineralogico Lombardo (10) +1 other reference |
| Guastoni et al. (2006) |
| Guastoni et al. (2006) +2 other references | |
| Luigi Chiappino data |
| Pelloux (1904) +1 other reference |
| Stara P. (1996) |
| Fernando Caboni et al. (2024) | |
| Fernando Caboni et al. (2024) | |
| Campostrini et al. (1999) |
| Mair (1996) |
| Conedera M. et al. (2016) |
| Ferretti et al. (2018) |
| Bortolozzi et al. (2013) |
| Bortolozzi et al. (2021) |
| Erica Bittarello +4 other references |
| Bazzoni et al. (2007) |
| Matteo Chinellato |
| www.comune.pisa.it (2000) | |
| |
| Muenchener Micromounter-Lithothek |
Japan | |
| Sadanaga et al. (1974) |
| Kikukawa et al. (1999) |
Kazakhstan | |
| Chukhrov (1945) +1 other reference |
| Palache et al. (1951) | |
| Sumin (1941) | |
| Palache et al. (1951) |
Morocco | |
| Favreau et al. (2006) |
| Georges FAVREAU collection |
New Zealand | |
| Essence of Microscope |
Norway | |
| |
Poland | |
| Siuda (2001) |
Portugal | |
| |
| Alves (n.d.) |
| Hugo Lobo Collection |
Romania (TL) | |
| Palache et al. (1951) +1 other reference |
| on public display of the ... | |
Russia | |
| CLAUDE jean marie Collection |
| Mikhailov et al. (2021) |
| Sumin (1941) +1 other reference |
| Yakhontova +4 other references |
Slovakia | |
| ฤech et al. (1965) |
| Pauliลก | |
South Africa | |
| Swiegers (1948) |
| Jacko Schonken collection photo ID ... | |
| Atanasova et al. (2016) |
| Reeks (2007) |
| Cairncross (2004) |
| Steffen Michalski Collection - found ... |
| Palache et al. (1951) +1 other reference | |
Spain | |
| Pesudo Verde Collection +2 other references |
| Valladares et al. (2021) |
| Queneau (n.d.) |
| Favreau (n.d.) +1 other reference |
| FMF Forum |
| Calvo Rebollar (2014) |
| Calvo Rebollar (2014) |
| Calvo Rebollar (2012) |
| Analyzed by XRD by Dr. Joan Vinals (Barcelona) +1 other reference |
| Mineralogistes de Catalunya (2/3) |
| Pedro Mingueza et al. (2022) |
| Joan Rosell (02/2016) |
| J. Rosell (02/2016) +1 other reference | |
Sweden | |
| Detlef Heilwagen collection |
Switzerland | |
| Stalder et al. (1998) |
| Malcherek et al. (2024) +1 other reference |
| Stalder et al. (1998) |
| Stalder et al. (1998) |
| Kolitsch (1998) |
| Stalder et al. (1998) |
| Stalder et al. (1998) |
| Ansermet (2012) |
| EDXS analyses | |
| 86. (in German) +2 other references | |
UK | |
| Day (1999) |
| Golley et al. (1995) |
| Golley et al. (1995) |
| Steve Rust collection |
| Golley et al. (1995) +1 other reference |
| Golley et al. (1995) |
| Golley et al. (1995) |
| Golley et al. (1995) |
| |
| Collection Richard De Nul | |
| Camm et al. (1991) | |
| Golley et al. (1995) |
| Hartley (1984) +1 other reference |
| Cooper et al. (1990) +1 other reference | |
| Barry Pitt personally collected from the waste dumps in 2022 Specimen A โ Sky blue material. XRD no. NMW X-3884 = probable cyanotrichite (far from a perfect match) |
| |
| Day (1999) |
| Palache et al. (1951) |
Ukraine | |
| Geologiya SSSR. Poleznye iskopaemye (The geology of USSR. Commercial mineral) |
USA | |
| Anthony et al. (1995) |
| Richard Graeme |
| Luetcke (n.d.) |
| Anthony et al. (1995) | |
| Anthony et al. (1995) | |
| Rogers (1922) +4 other references |
| Genth (1890) +1 other reference |
| Anthony et al. (1995) | |
| Phil Partington +1 other reference |
| Raman analyzed at the University of ... |
| Anthony et al. (1995) |
| Anthony et al. (1995) | |
| Murdoch (1966) |
| Housley R. |
| Dana 6:1089. |
| Eckel et al. (1997) |
| Eckel et al. (1997) |
| Rosemeyer (2010) |
| James Bauer's Collection |
| Ream (2004) |
| Ream (1995) | |
| Ream (1995) | |
| Castor et al. (2004) |
| Castor et al. (2004) | |
| Castor et al. (2004) |
| Newmont Mining Corporation |
| Jensen et al. (1995) |
| Dr. William S. Wise presentation to ... +1 other reference |
| Castor et al. (2004) |
| Castor et al. (2004) | |
| Castor et al. (2004) | |
| Castor et al. (2004) | |
| Pullman et al. (1999) |
| Castor et al. (2004) |
| Palache et al. (1951) +1 other reference |
| Castor et al. (2004) |
| Castor et al. (2004) |
| Franklin Mineral Species Committee |
| Franklin Mineral Species Committee |
| R&M 71:1 p66-68 +1 other reference |
| Northrop et al. (1996) |
| M Massis collection +1 other reference |
| Philip Simmons Collection | |
| Tiny Minerals | |
| Min News 21:8 p 8 | |
| J. M. S. (1960) +1 other reference | |
| Gibbs (1989) | |
| Loughlin et al. (1942) +1 other reference | |
| Dana 6:1092 +1 other reference |
| Bullock (1981) | |
| Collected by Andrew Turner. | |
| Bullock (1981) | |
| Page et al. (1956) +2 other references |
| University of Utah XRD Report 01/25/16 |
| Thorne (n.d.) +1 other reference |
| Kampf et al. (2018) | |
| USGS TEI #514 |
| Thorne (n.d.) |
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The
Hilarion Mine, Kamariza Mines, Agios Konstantinos, Lavreotiki, East Attica, Attica, Greece